Question about Xiaomi Air Compressor 2

You are reading it incorrectly; the preset mode does not limit the maximum pressure to 65 psi. The Xiaomi Air Compressor 2 can inflate up to 150 psi, which covers your road bike wheel recommendation of 85-115 psi. It has six preset modes, and manual mode allows you to set and save your desired pressure, so you can set it to your required psi without limitation at 65 psi.