La Roche-Posay's "Effaclar H Iso-Biome" product is designed primarily for the face, but is not specifically recommended for application around the eyes. The ingredients and formulation are designed to treat acne-prone and fragile skin on the face, rather than the delicate skin around the eyes.
It is recommended to apply to the face after cleansing, but it is preferable to choose a product specifically designed for the delicate area around the eyes to avoid any irritation or sensitivity.